Product ID:MS-180/CO2 TF SOLVENT
MSDS Date:05/01/2000
FSC:6850
NIIN:00-105-3084
Status Code:A
MSDS Number: CLMGP

MILLER-STEPHENSON CHEMICAL CO INC

55 BACKUS AVE/GEORGE WASHINGTON HWY
DANBURY, CT 06810
US

Emergency Phone: 203-797-2212

Info Phone: 203-743-4447

Preparer: NOT PROVIDED

Cage: 18598

MILLER-STEPHENSON CHEMICAL CO INC

950 DANBURY, CT 06810 US

Telephone: 203-743-4447

Cage: 18598

TRICHLOROTRIFLUOROETHANE

CAS: 76-13-1

RTECS: KJ4000000

OSHA PEL 7600 MG/M3;1000 PPM

ACGIH TLV: 7670 MG/M3;1000 PPM

CARBON DIOXIDE

CAS: 124-38-9

RTECS: FF6400000

OSHA PEL 9000 MG/M3;5000 PPM

ACGIH TLV: 9000 MG/M3;5000 PPM

LD50 LC50 Mixture:LD50 (ORAL, RAT) 43,000 MG/KG
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: VAPOR IS HEAVIER THAN AIR
AND CAN CAUSE SUFFOCATION BY REDUCING OXYGEN AVAILABLE FOR
BREATHING. BREATHING HIGH CONCENTRATIONS OF VAPOR MAY CAUSE LIGHT
HEADEDNESS, GIDDINESS, SHORTNESS OF B REATH AND MAY LEAD TO
NARCOSIS, CARDIOVASCULAR IRREGULARITIES, UNCONSCIUSNESS OR DEATH.
SKIN: NOT A CORROSIVE OR IRRITANT AFTER SINGLE CONTACT. HOWEVER,
REPEATED LIQUID CONTACT CAN CAUSE DEFATTING OF THE SKIN RESULTING
IN IRRITATION. THIS MATERIAL IS POORLY ABSORBED THROUGH THE SKIN.
EYE: LIQUID CONTACT CAN CAUSE DISCOMFORT, USUALLY NO EXTENDED
EFFECT. ORAL: ALTHOUGH ORAL TOXICITY IS LOW INGESTION OF FREON TF
IS TO BE AVOIDED.
Explanation of Carcinogenicity:FREON TF IS NOT LISTED AS A CARCINOGEN
BY IARC, NTP, OR OSHA. BASED ON ANIMAL STUDIES AND HUMAN
EXPERIENCE, THIS MIXTURE POSES NO HAZARD TO MAN RELATIVE TO
SYSTEMIC TOXICITY, CARCINOGENICITY, MUTAGENI CITY, OR
TERATOGENICITY WHEN OCCUPATIONAL EXPOSURES ARE BELOW ITS
RECOMMENDED TLV.
Effects of Overexposure:INHALATION: BREATHING HIGH CONCENTRATIONS OF
VAPOR MAY CAUSE LIGHT HEADEDNESS, GIDDINESS, SHORTNESS OF BREATH
AND MAY LEAD TO NARCOSIS, CARDIOVASCULAR IRREGULARITIES,
UNCONSCIUSNESS OR DEATH. REPEATED LIQUID CONTACT CAN CAUSE
DEFATTING OF THE SKIN RESULTING IN IRRITATION. EYE: LIQUID CONTACT
CAN CAUSE DISCOMFORT.
Medical Cond Aggravated by Exposure:NOT PROVIDED

First Aid:INHALATION: REMOVE TO FRESH AIR, CALL PHYSICIAN. IF NOT
BREATHING, GIVE ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH.
IF BREATHING IS DIFFICULT, GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR
SIMILAR DR UGS. EYE: IMMEDIATELY FLUSH WITH WATER FOR AT LEAST 15
MINUTES. CALL A PHYSICIAN. SKIN: FLUSH WITH WATER. GET MEDICAL
ATTENTION IF IRRITATION IS PRESENT. ORAL: THE COMPOUND IS NOT
LIKELY TO BE HAZARDO US BY INGESTIONS. HOWEVER, CONSULT A PHYSICIAN
IF NECESSARY. DO NOT INDUCE VOMITING AS THE HAZARD OF ASPIRATING
THE MATERIAL INTO THE LUNGS IS A GREATER HAZARD THAN ALLOWING IT TO
PROGRESS THROUGH INT ESTINAL TRACT.

Flash Point Method:TOC
Flash Point:NONE
Autoignition Temp:Autoignition Temp Text:N/D
Extinguishing Media:NON-FLAMMABLE.
Fire Fighting Procedures:SELF-CONTAINED BREATHING APPARATUS (SCBA) MAY
BE REQUIRED IF AEROSOLS RUPTURE AND CONTENTS ARE SPILLED UNDER FIRE
CONDITIONS.
Unusual Fire/Explosion Hazard:PRESSURIZED AEROSOL CONTAINERS AT
ELEVATED TEMPERATURES MAY VENT, RUPTURE, OR BURST AND ADD TO FLYING
AND FALLING DEBRIS. DECOMPOSITION MAY OCCUR.

Spill Release Procedures:VENTILATE AREA. REMOVE OPEN FLAMES OR RED HOT
SURFACES. ALLOW TO EVAPORATE.
Neutralizing Agent:NOT RELEVANT

Handling and Storage Precautions:DO NOT STORE NEAR SOURCES OF HEAT, IN
DIRECT SUNLIGHT OR WHERE TEMPERATURES EXCEED 120F/49C. DO NOT
PUNCTURE OR DAMAGE CONTAINERS. ROTATE STOCK TO SHELF LIFE OF ONE
YEAR.
Other Precautions:NOT PROVIDED

Respiratory Protection:UNDER NORMAL MANUFACTURING CONDITIONS NO
RESPIRATORY PROTECTION IS REQUIRED WHEN USING THIS PRODUCT.
SELF-CONTAINED BREATHING APPARATUS (SCBA) IS REQUIRED IF A LARGE
SPILL OCCURS.
Ventilation:LOCAL EXHAUST SHOULD BE USED WHEN LARGE AMOUNTS ARE
RELEASED. MECHANICAL VENTILATION SHOULD BE USED IN LOW PLACES.
Protective Gloves:BUTYL GLOVES SHOULD BE USED TO AVOID PROLONGED OR
REPEATED EXPOSURE.
Eye Protection:CHEMICAL SPLASH GOGGLES SHOULD BE AVAILABLE FOR USE AS
NEEDED.
Other Protective Equipment:NOT PROVIDED
Work Hygienic Practices:DO NOT SPRAY LIQUID ON SKIN.
Supplemental Safety and Health
ABBREVIATION: N/A = NOT APPLICABLE. N/AV = NOT AVAILABLE. N/K =
UNKNOWN. N/P = NOT PROVIDED. N/R = NOT RELEVANT. N/D = NOT
DETERMINED. N/E = NOT ESTABLISHED. CNS = CENTRAL NERVOUS SYSTEM. GI
= GASTROI NTESTINAL. SCBA = SELF CONTAINED BREATHING APPARATUS.

HCC:V2
NRC/State Lic Num:NOT RELEVANT
Boiling Pt:=47.8C, 118.F
Melt/Freeze Pt:M.P/F.P Text:NOT PROVIDED
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:334 MMHG@77F
Vapor Density:2.9
Spec Gravity:1.57
Viscosity:NOT PROVIDED
Evaporation Rate & Reference:(CCL4=1):2.8
Solubility in Water:NEGLIGIBLE
Appearance and Odor:CLEAR AND COLORLESS. LIQUID, FAINT SOLVENT ODOR
Percent Volatiles by Volume:100
Corrosion Rate:NOT PROVIDED

Stability Indicator/Materials to Avoid:YES
ALKALI OR ALKALINE EARTH METALS, POWDERED AL, ZN, BE, ETC.
Stability Condition to Avoid:MATERIAL IS STABLE. HOWEVER, AVOID
SPRAYING NEAR OPEN FLAMES OR RED HOT SURFACES. DO NOT HEAT AEROSOL
CONTAINERS ABOVE 49C/120F.
Hazardous Decomposition Products:THIS COMPOUND CAN BE DECOMPOSED BY
HIGH TEMPERATURES (OPEN FLAMES, GLOWING METAL SURFACES, ETC.)
FORMING HYDROCHLORIC AND HYDROFLUORIC ACIDS - POSSIBLY CARBONYL
HALIDES.

Waste Disposal Methods:DO NOT PUNCTURE OR INCINERATE AEROSOL CANS.
COMPLY WITH FEDERAL, STATE AND LOCAL REGULATIONS.

Toxicological Information:LC50 RATS 52,000 PPM/4 HRS. SKIN RABBIT ALD >
11,000 MG/KG. LD 50 RATS 43,000 MG/KG.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:NOT PROVIDED

Transport Information:NOT PROVIDED

SARA Title III Information:SARA TITLE III STATUS: REPORTED/INCLUDED.
SARA HAZARD CATEGORIES: ACUTE: YES. CHRONIC: NO. FIRE: NO.
REACTIVE: NO. PRESSURE: YES. EXTREMELY HAZARDOUS SUBSTANCES: NONE.
CERCLA HAZARDOUS SUBSTANCES: NO. TOXIC CHEMICALS: YES.
TRICHLOROTRIFLUOROETHANE COMPONENT ONLY.
Federal Regulatory Information:TSCA INVENTORY STATUS: REPORTED.
State Regulatory Information:NOT PROVIDED