Product ID:CHEMSEARCH 444, 0326
MSDS Date:01/04/1993
FSC:6850
NIIN:00N064553
MSDS Number: BZKJR

NATIONAL CHEMSEARCH DIV NCH CORP

IRVING, TX 75015
US

Emergency Phone: 214-438-1381

Info Phone: 214-438-1381

Preparer: K WOODY

Cage: DO481

NCH CORP CHEMSEARCH DIV

152170 IRVING, TX 75015 US

Telephone: 972-438-1381/800-527-9919

Cage: 0A782

CYCLOHEXYLAMINE (SARA 302)

CAS: 108-91-8

RTECS: GX0700000

OSHA PEL 10 PPM

ACGIH TLV: 10 PPM; 9495

MORPHOLINE

CAS: 110-91-8

RTECS: QD6475000

OSHA PEL S, 20 PPM

ACGIH TLV: S, 20 PPM; 9495

CAREFULLY IN CASE OF ORAL POISONING. EXPOSURE TO

RTECS: 9999999ZZ

CORNEAL EPITHELIUM.

RTECS: 9999999ZZ

VENTILATION IS NEEDED AT POINTS WHERE VAPORS CAN BE

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 156 MG/KG 2.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: INGEST:MODERATELY TOXIC. MAY
CAUSE BURNS OF MOUTH & THROAT. ABDOMINAL PAIN, NAUSEA, VOMITING, &
DIARRHEA. INHAL:VAPORS ARE IRRITATING & MAY CAUSE NAUSEA/VOMITING.
SKIN:CAUSES CHEMICAL BURNS. EY ES:CAUSES MODERATE CORNEAL INJURY.
VAPOR MAY CAUSE TEMPORARY DISTURBANCES OF VISION (SEE NOTES TO MD)
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT.
Effects of Overexposure:HLTH HAZ:CHRONIC: SKIN ABSORBTION:PRLNGD/RPTD
EXPOS MAY RESLT IN ABSORBTION OF HARMFUL AMTS OF MATL. INHAL:PRLNGD
OVEREXP CAN PROMOTE SENSIT OF RESP TRACT, RSLTG IN POTNTL ASTHMATIC
RESPONSE & INFLAMM /FIBROTIC PULM DISEASE. SKIN CNTCT:EXPOS MAY
RSLT IN SENSIT OF SKIN BECAUSE OF ITS IRRIT PROPERTIES, (SUPDAT)
Medical Cond Aggravated by Exposure:MAY AGGRAVATE EXISTING DERM.

First Aid:INHAL:REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, OXYGEN MAY BE
GIVEN, CALL MD. EYE:IMMED FLUSH EYES W/PLENTY OF H*2O FOR AT LEAST
15 MIN. GET MED ATTN, PREF AN OPTHAMOLOGIST, PROMPTLY. SKIN:REMOVE
CONTAM D CLTHG & FLUSH SKIN W/PLENTY OF H*2O. CALL MD. INGEST:DO
NOT INDUCE VOMIT. GIVE LRG QUANTITIES OF H*2O TO DILUTE MATL, CALL
MD. IF VOMIT OCCURS, GIVE H*2 . NOTE TO MD:THERE IS NO SPECIFIC.
(SUPDAT)

Flash Point Method:TCC
Flash Point:130F,54C
Extinguishing Media:FOAM, ALCOHOL FOAM, CO*2, DRY CHEMICAL, WATER
SPRAY.
Fire Fighting Procedures:USE NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP.
DO NOT SPRAY POOL FIRES DIRECTLY. SOLID STREAM OF H*2O DIRECTED
INTO HOT, BURNING LIQ CAN CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:NOT APPLICABLE.

Spill Release Procedures:WEAR SUTIBLE PROTECTIVE EQUIPMENT. AVOID
CONTACT WITH LIQUID AND VAPORS. SMALL SPILLS MAY BE FLUSHED W/LARGE
AMTS OF H*2O (< THAN 5 GALLONS). LARGE SPILLS; FLUSH W/ H*2O & USED
SAND AS AN ABSORBANT. R EMOVE TO CLOSED CONTAINERS.

Handling and Storage Precautions:STORAGE TEMPERATURE: 120F MAX, 35F
MIN. STORE INDOOR.
Other Precautions:DO NOT GET IN EYES, ON SKIN, OR CLOTHING. AVOID
BREATHING VAPOR. KEEP CONTAINER CLOSED. USE WITH ADEQUATE
VENTILATION. WASH THOROUGHLY AFTER HANDLING. DO NOT TAKE
INTERNALLY. EMPTY CONTAINERS MAY CONT AIN HAZARDOUS RESIDUES.

Respiratory Protection:NIOSH/MSHA APPROVED SELF-CONTAINED BREATHING
APPARATUS IN HIGH VAPOR CONCENTRATIONS.
Ventilation:THIS PROD SHOULD BE CONFINED W/IN CLSD EQUIP. IN WHICH CASE
GEN (MEC) ROOM VENT SHOULD BE SATIS. SPECIAL, LOCAL(ING 5)
Protective Gloves:RUBBER GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS(SUPDAT)
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . CHEMICAL APRON.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: SPLATTERING. OXIDES OF NITROGEN WILL BE EVOLVED. EYE
PROT: & FULL LENGTH FACESHIELD. EFTS OF OVEREXP:EYE CNTCT:MAY CAUSE
PERM DMG TO EYES. FIRST AID PROC:ANTIDOTE. TREATMENT SHOULD BE
DIRECTED AT CONTROL OF SYMP & CLINCIALCONDTNS. DUE TO IRRITANT
NATURE OF MATL. STOMACH SHOULD BE EVACUATED (ING 3)

Boiling Pt:B.P. Text:273F,134C
Vapor Pres:150
Vapor Density:3.4
Spec Gravity:1.03 (H*2O = 1)
pH:12.2
Solubility in Water:APPRECIABLE
Appearance and Odor:WATER-WHITE, AMINE ODOR
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
CONTAMINATION W/MINERAL/ORGANIC ACIDS, OXIDIZING MATLS, ALDEHYDES,
KETONES, ORGANIC MALIDES, SODIUM NITRITE, & NITRATES.
Stability Condition to Avoid:NONE SPECIFIED BY MANUFACTURER.
Hazardous Decomposition Products:BURNING CAN PRODUCE CARBON MONOXIDE
AND/OR CARBON DIOXIDE AND OXIDES OF NITROGEN.

Waste Disposal Methods:INCINERATE IN A FURNACE WHERE PERMITTED UNDER
APPROPRIATE FEDERAL, STATE, AND LOCAL REGULATIONS. ALSO SEE SPECIAL
PROTECTION INFORMATION SECTION.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.