Product ID:FREON 113
MSDS Date:10/12/1990
FSC:6810
NIIN:00F032008
MSDS Number: BSPPQ

Emergency Phone: 201-796-7100/201-796-7523

Info Phone: 201-796-7100/201-796-7523

Preparer: GASTON L PILLORI

Cage: 1B464

Telephone: 201-796-7100

Cage: 1B464

FREON 113, 1,1,2,-TRICHLORO-1,2,2,-TRIFLUOROETHANE,

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 100%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

LD50 LC50 Mixture:ORAL LD50 (RAT): 43 GM/KG
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION: SIMPLE ASPHYXIANT &
NARCOTIC. MILD IRRITATION OF MUCOUS MEMBRANES. CNS DEPRESSION.
SKIN: IRRITATION, DERMATITIS. INGESTION: SYSTEM TOXICITY MAY OCCUR
AS IN ACUTE INHALATION. EYES: IRRITATI ON.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:INHALATION: DROWSINESS, ARRHYTHMIAS,
SOMNOLENCE, HEAVINESS IN THE HEAD, IMPAIRED MANUAL DEXTERITY &
VIGILANCE, LOSS OF CONCENTRATION, SUDDEN DEATH FROM VENTRICULAR
FIBRILLATION. SKIN: DRYING, CRACKING . EYES: MILD CONJUNCTIVITIS,
MININMAL CORNEAL DULLNESS. INGESTION: CYANOSIS, PNEUMONITITS,
DIARRHEA, RECTAL IRRITATION.
Medical Cond Aggravated by Exposure:SKIN DISORDERS, IMPAIRED
CARDIOVASCULAR FUNCTION, CARDIAC ARRYTHMIAS, IMPAIRED RESPIRATORY
FUNCTION.

First Aid:INHALATION: REMOVE TO FRESH AIR. IF BREATHING DIFFICULT OR
STOPPED, GIVE OXYGEN OR CPR. SKIN: WASH W/SOAP & WATER FOR 20 MINS.
EYES: WASH W/WATER FOR 20 MINS. INGESTION: IF VOMITING OCCURS, KEEP
HEAD BELOW HIPS TO PREVENT ASPIRATION. OBTAIN MEDICAL ATTENTION IN
ALL CASES.

Extinguishing Media:DRY CHEMICAL, CO2, HALON, WATER SPRAY, FOAM, FOG
Fire Fighting Procedures:NEGLIGIBLE FIRE HAZARD WHEN EXPOSED TO HEAT OR
FLAME. MOVE CONTAINERS FROM FIRE AREA IF POSSIBLE. DON'T SCATER
SPILLED PRODUCT W/WATER STREAMS. DIKE AREA.

Spill Release Procedures:DIKE WATER FROM FIRE CONTROL FOR LATER
DISPOSAL.

Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLES.

Respiratory Protection:WEAR SUPPLIED AIR OR SCBA WITH FULLFACEPIECE
MASK & ORGANIC VAPOR CANISTER.
Ventilation:LOCAL EXHAUST
Protective Gloves:RECOMMENDED
Eye Protection:SPLASH & DUST PROOF FACESHIELD/GOGGLES
Other Protective Equipment:IMPERVIOUS CLOTHING & EQUIPMENT TO PREVENT
SKIN CONTACT. EYES WASH & SHOWER IN AREA.
Work Hygienic Practices:REMOVE CONTAMINATED CLOTHING & SHOES
IMMEDIATELY.
Supplemental Safety and Health
AUTOIGNITION TEMP: 1256F. CONT'D MATERIALS TO AVOID: PLASTIC & RUBBER
COATINGS, POTASSIUM, SAMARIUM, SODIUM & SODIUM-POTASSIUM ALLOY,
POWDERED TITANIUM, ZINC.

Boiling Pt:B.P. Text:114.4F
Melt/Freeze Pt:M.P/F.P Text:55.8F
Vapor Pres:284
Vapor Density: 6
Spec Gravity:1.6
Evaporation Rate & Reference:(ACETONE = 1): 0.45
Solubility in Water:NEGLIGIBLE
Appearance and Odor:COLORLESS LIQUID, AMMONIA-LIKE ODOR AT HIGH
CONCENTRATIONS

Stability Indicator/Materials to Avoid:YES
ACTIVE & ALKALI METALS, POWDERED ALUMINUM & BARIUM, DERYLLIUM, CALCIUM,
POWDERED LITHIUM, MAGNESIUM, (SEE SUPP)
Stability Condition to Avoid:HEAT
Hazardous Decomposition Products:TOXIC & CORROSIVE FUMES OF CHLORIDES &
FLUORIDES, TOXIC OXIDES OF CARBON

Waste Disposal Methods:DISPOSE I/A/W LOCAL, STATE & FEDERAL
REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.