Product ID:PERMABOND (R) 102 82-9808
MSDS Date:04/16/1990
FSC:8040
NIIN:00-142-9193
MSDS Number: BSHRQ

Emergency Phone: 908-685-5000

Info Phone: 908-685-5000

Preparer: PHILIP A. TOSCANO

Cage: 85091

Telephone: 908685-5306

Cage: 85091

ETHYL CYANOACRYLATE

CAS: 7085-85-0

Fraction By Weight: > 1%

ACGIH TLV: 2 PPM; STEL 4 PPM

NIL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:UNKNOWN IARC:UNKNOWN OSHA:NO
Health Hazards Acute and Chronic:ACUTE: EYE: ON CONTACT, WILL BOND
EYELIDS TOGETHER. VAPORS ARE LACHRYMATORY. SKIN CONTACT: ON
CONTACT, IMMEDIATE BONDING OF SKIN WILL OCCUR. FREQUENT OR
PROLONGED CONTACT IRRITATE SKIN. INHALATION: VA PORS IRRITATING TO
RESPIRATORY SYSTEM &NASAL PASSAGES. INGESTION: ON CONTACT,
IMMEDIATE BONDING OF MOUTH COULD OCCUR.

First Aid:EYE: FLUSH WITH LARGE AMOUNTS OF WATER WHILE HOLDING EYELIDS
OPEN. GET MED AID IMMED. CURED ADHESIVE WILL NOT BOND WELL TO
SURFACE OF EYE, BUT CORNEAL DAMAGE FROM ABRASION MAY RESULT. SKIN:
NO ATTEMPT SHOULD BE MADE TO REMOVE MATERIAL FROMSKIN OR TO REMOVE
CONTAMINATED CLOTHING, AS THE BONDED SKIN CAN EASILY BE TORN. WASH
W/LARGE VOLUMES OF SOAP/WATER WHILE FLEXING BONDED SKIN PARTS. THIS

Flash Point Method:SCC
Flash Point:167F,75C
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:FIRE FIGHTERS SHOULD BE EQUIPPED WITH SELF-
CONTAINED BREATHING APPARATUS TO PROTECT AGAINST POTENTIALLY TOXIC
AND IRRITATING FUMES.
Unusual Fire/Explosion Hazard:CLOTHS USED TO WIPE UP SPILLS CAUSE RAPID
POLYMERIZATION THAT COULD GENERATE SUFFICIENT HEAT TO IGNITE THE
CLOTH. COMBUSTION MAY RELEASE NOXIOUS OR TOXIC VAPORS

Spill Release Procedures:SMALL SPILLS: WIPE UP W/CLOTH. IMMEDIATELY
SOAK CLOTH W/WATER TO POLYMERIZE THE ADHESIVE. CAUTION! CLOTH
CONTAINING ADHESIVE MAY UNDERGO AUTO IGNITION IF NOT SOAKED
W/WATER. LARGE SPILLS: FLOOD AREA W /WATER. WHEN CURED, REMOVE FILM
W/SCRAPER.

Handling and Storage Precautions:STORAGE TEMPERATURE LESS THAN 80 F.
STORE IN COOL, DRY AREA AWAY FROM HEAT, SPARKS OR FIRE.
Other Precautions:DON'T WEAR CONTACT LENSES WHEN WORKING WITH THIS
MATERIAL.

Respiratory Protection:AVOID PROLONGED OR REPEATED BREATHING OF VAPOR
OR MISTS. IF EXPOSURE MAY OR DOES EXCEED OCCUPATIONAL EXPOSURE
LIMITS, USE A NIOSH APPROVED RESPIRATOR TO PREVENT OVEREXPOSURE &
WHEN CLEANING LARGE SPIL LS.
Ventilation:LOCAL
Protective Gloves:POLETHYLENE, NOT RUBBER OR CLOTH
Eye Protection:SAFETY GLASSES, GOGGLES OR FACE SHIELD
Other Protective Equipment:NO SPECIAL CLOTHING REQUIRED FOR LOW VOLUME
ACTIVITY.
Work Hygienic Practices:REMOVE & WASH CONTAMINATED CLOTHING CAREFULLY
BEFORE REUSE.
Supplemental Safety and Health
PROCEDURE WILL SLOWLY RELEASE BONDED AREAS. DON'T MECHANICALLY REMOVE
CURED ADHESIVE OR ATTEMPT TO PULL SKIN APART. INHALATION: REMOVE TO
FRESH AIR. IF BREATHING IS DIFFICULT, GIVE OXYGEN. IF BREATHIN G
HAS STOPPED, GIVE CPR. GET MEDICAL ATTENTION. INGESTION: IMMEDIATE
BONDING OF MOUTH WILL OCCUR. GET MEDICAL AID.

HCC:V4
Boiling Pt:B.P. Text:140F,60C
Vapor Pres:0.3 @ 68F
Vapor Density:>1 AIR = 1
Spec Gravity:1.050 WATER = 1
Viscosity:100 CPS
Solubility in Water:INSOLUBLE
Appearance and Odor:TRANSPARENT LIQUID; PUNGENT ODOR
Percent Volatiles by Volume:NIL

Stability Indicator/Materials to Avoid:YES
WATER, ALKALINE MATERIALS, PEROXIDES
Stability Condition to Avoid:CONTAMINATION OF ADHESIVE WITH ALKALINE
MATERIALS, PEROXIDES OR WATER CAN RESULT IN RAPID POLYMERIZATION.
IN LARGE
Hazardous Decomposition Products:DECOMPOSES UPON HEATING TO RELEASE
TOXIC FUMES OF NITROGEN OXIDES, CARBON MONOXIDE AND CARBON DIOXIDE.
Conditions to Avoid Polymerization:QUANTITIES, THIS COULD LEAD TO AN
UNCONTROLLABLE RISE IN TEMPERATURE & A BUILDUP OF PRESSURE IN
CLOSED CONTAINERS.

Waste Disposal Methods:WASTE DISPOSAL SHOULD BE IN ACCORDANCE WITH
EXISTING LOCAL, STATE & FEDERAL ENVIRONMENTAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.